TY - JOUR
T1 - 烃转化过程中的氢转移反应
AU - Li, Fang
AU - Wang, Yiran
AU - Zhang, Penghe
AU - Liu, Yueming
AU - He, Mingyuan
N1 - Publisher Copyright:
© 2025 Materials China. All rights reserved.
PY - 2025/6/25
Y1 - 2025/6/25
N2 - Green carbon science has become the scientific foundation for carbon neutrality. The evolution of C—C and C—H bonds during the hydrocarbon conversion process runs throughout the entire carbon cycle. In the process of C—C bond evolution, the breaking and formation of C—H bonds are inevitable, that is, hydrogen transfer reactions also exist in this process. This paper focuses on hydrogen transfer reactions in the hydrocarbon conversion process, reviewing from three dimensions: mechanisms of hydrogen transfer reactions, regulation of hydrogen transfer reactions, and application of hydrogen transfer reactions in product-oriented hydrocarbon conversion processes. From the perspective of hydrogen transfer reactions, it envisions the reasonable roles of different carbon resources (fossil resources, biomass resources, waste plastic resources, and CO2 resources) in their efficient conversion as hydrogen acceptors or hydrogen donors. Biomass and water, as potential sustainable hydrogen donors, will play a core role in the construction of future energy systems guided by green carbon science.
AB - Green carbon science has become the scientific foundation for carbon neutrality. The evolution of C—C and C—H bonds during the hydrocarbon conversion process runs throughout the entire carbon cycle. In the process of C—C bond evolution, the breaking and formation of C—H bonds are inevitable, that is, hydrogen transfer reactions also exist in this process. This paper focuses on hydrogen transfer reactions in the hydrocarbon conversion process, reviewing from three dimensions: mechanisms of hydrogen transfer reactions, regulation of hydrogen transfer reactions, and application of hydrogen transfer reactions in product-oriented hydrocarbon conversion processes. From the perspective of hydrogen transfer reactions, it envisions the reasonable roles of different carbon resources (fossil resources, biomass resources, waste plastic resources, and CO2 resources) in their efficient conversion as hydrogen acceptors or hydrogen donors. Biomass and water, as potential sustainable hydrogen donors, will play a core role in the construction of future energy systems guided by green carbon science.
KW - green carbon science
KW - hydrocarbon conversion
KW - hydrogen acceptors
KW - hydrogen donors
KW - hydrogen transfer reaction
UR - https://www.scopus.com/pages/publications/105010430938
U2 - 10.11949/0438-1157.20241301
DO - 10.11949/0438-1157.20241301
M3 - 文献综述
AN - SCOPUS:105010430938
SN - 0438-1157
VL - 76
SP - 2483
EP - 2504
JO - Huagong Xuebao/CIESC Journal
JF - Huagong Xuebao/CIESC Journal
IS - 6
ER -