惰性键与二氧化碳的电化学羧化反应研究

Xiaotong Gao; Yuqing Zhong; Nan Feng; Ying Sun; Deyong Yang; Feng Zhou

doi:10.6023/cjoc202406045

惰性键与二氧化碳的电化学羧化反应研究

Translated title of the contribution: Recent Advances in Electrochemical Carboxylation of Inert Chemical Bonds with Carbon Dioxide

Xiaotong Gao^*
, Yuqing Zhong
, Nan Feng
, Ying Sun
, Deyong Yang
, Feng Zhou^*

^*Corresponding author for this work

School of Chemistry and Molecular Engineering

Chongqing University of Science and Technology
East China Normal University

Research output: Contribution to journal › Review article › peer-review

11 Scopus citations

Abstract

Carbon dioxide (CO₂) is a green and renewable C1 synthon, and the direct carboxylation of inert chemical bonds with CO2 could afford high value-added carboxylic acid derivatives from simple molecules, which feature both atomic and step economies. Organic electrosynthesis is a green synthesis technology using electrons as "reagents", and the development of electrochemical carboxylation of inert bonds with CO₂ has become a hot research topic in recent years. The recent progress on the electroreductive carboxylation of inert bonds with CO₂ is summarized, including C—H, C—C, C—O, and C—F single bonds. The mechanism and application of these reactions are emphatically discussed, and the challenges and development trends in this field are also covered.

Translated title of the contribution	Recent Advances in Electrochemical Carboxylation of Inert Chemical Bonds with Carbon Dioxide
Original language	Chinese (Traditional)
Pages (from-to)	3043-3062
Number of pages	20
Journal	Chinese Journal of Organic Chemistry
Volume	44
Issue number	10
DOIs	https://doi.org/10.6023/cjoc202406045
State	Published - 25 Oct 2024

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SDG 7 Affordable and Clean Energy

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Cite this

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title = "惰性键与二氧化碳的电化学羧化反应研究",

abstract = "Carbon dioxide (CO2) is a green and renewable C1 synthon, and the direct carboxylation of inert chemical bonds with CO2 could afford high value-added carboxylic acid derivatives from simple molecules, which feature both atomic and step economies. Organic electrosynthesis is a green synthesis technology using electrons as {"}reagents{"}, and the development of electrochemical carboxylation of inert bonds with CO2 has become a hot research topic in recent years. The recent progress on the electroreductive carboxylation of inert bonds with CO2 is summarized, including C—H, C—C, C—O, and C—F single bonds. The mechanism and application of these reactions are emphatically discussed, and the challenges and development trends in this field are also covered.",

keywords = "carbon dioxide, carboxylic acids, electrochemistry, inert chemical bonds, reductive carboxylation",

author = "Xiaotong Gao and Yuqing Zhong and Nan Feng and Ying Sun and Deyong Yang and Feng Zhou",

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doi = "10.6023/cjoc202406045",

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TY - JOUR

T1 - 惰性键与二氧化碳的电化学羧化反应研究

AU - Gao, Xiaotong

AU - Zhong, Yuqing

AU - Feng, Nan

AU - Sun, Ying

AU - Yang, Deyong

AU - Zhou, Feng

PY - 2024/10/25

Y1 - 2024/10/25

N2 - Carbon dioxide (CO2) is a green and renewable C1 synthon, and the direct carboxylation of inert chemical bonds with CO2 could afford high value-added carboxylic acid derivatives from simple molecules, which feature both atomic and step economies. Organic electrosynthesis is a green synthesis technology using electrons as "reagents", and the development of electrochemical carboxylation of inert bonds with CO2 has become a hot research topic in recent years. The recent progress on the electroreductive carboxylation of inert bonds with CO2 is summarized, including C—H, C—C, C—O, and C—F single bonds. The mechanism and application of these reactions are emphatically discussed, and the challenges and development trends in this field are also covered.

AB - Carbon dioxide (CO2) is a green and renewable C1 synthon, and the direct carboxylation of inert chemical bonds with CO2 could afford high value-added carboxylic acid derivatives from simple molecules, which feature both atomic and step economies. Organic electrosynthesis is a green synthesis technology using electrons as "reagents", and the development of electrochemical carboxylation of inert bonds with CO2 has become a hot research topic in recent years. The recent progress on the electroreductive carboxylation of inert bonds with CO2 is summarized, including C—H, C—C, C—O, and C—F single bonds. The mechanism and application of these reactions are emphatically discussed, and the challenges and development trends in this field are also covered.

KW - carbon dioxide

KW - carboxylic acids

KW - electrochemistry

KW - inert chemical bonds

KW - reductive carboxylation

UR - https://www.scopus.com/pages/publications/85212349281

U2 - 10.6023/cjoc202406045

DO - 10.6023/cjoc202406045

M3 - 文献综述

AN - SCOPUS:85212349281

SN - 0253-2786

VL - 44

SP - 3043

EP - 3062

JO - Chinese Journal of Organic Chemistry

JF - Chinese Journal of Organic Chemistry

IS - 10

ER -

惰性键与二氧化碳的电化学羧化反应研究

Abstract

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