光助MIL-101(Fe)活化过氧化氢氧化洛克沙胂及同步吸附生成的砷酸根

Lin Feng Sang; Shan Shan Su; Zi Wei Gao; Wei Jin; Ya Ping Zhao

光助MIL-101(Fe)活化过氧化氢氧化洛克沙胂及同步吸附生成的砷酸根

Translated title of the contribution: Photoassisted MIL-101(Fe) activated hydrogen peroxide system for oxidative degradation of roxarsone and adsorption of in-situ formed arsenate

Lin Feng Sang
, Shan Shan Su
, Zi Wei Gao
, Wei Jin
, Ya Ping Zhao^*

^*Corresponding author for this work

School of Ecology and Environmental Sciences

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

An iron-based-organic framework (MIL-101(Fe)) was prepared using a simple one-pot method, aiming to simultaneously oxidize ROX through activating hydrogen peroxide and adsorption formed arsenate under simulated sunlight. The photoassisted MIL-101(Fe) (250mg/L) activating H₂O₂ (1.0mmol/L) system could remove 95.27% of ROX within 120min. Moreover, the arsenate (As(V)) formed in this system could be adsorbed onto the surface of MIL-101(Fe) with 84.14% of the total arsenic removal ratio. The main formed reactive oxygen species •OH and O₂^•- free radicals, attacked the As-C bond of ROX, generated As(V) and o-nitrophenol compounds and accelerated the removal process. The actual environment water matrix significantly promoted the removal ratio of ROX in this system.

Translated title of the contribution	Photoassisted MIL-101(Fe) activated hydrogen peroxide system for oxidative degradation of roxarsone and adsorption of in-situ formed arsenate
Original language	Chinese (Traditional)
Pages (from-to)	203-212
Number of pages	10
Journal	Zhongguo Huanjing Kexue/China Environmental Science
Volume	42
Issue number	1
State	Published - 20 Jan 2022

Cite this

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title = "光助MIL-101(Fe)活化过氧化氢氧化洛克沙胂及同步吸附生成的砷酸根",

abstract = "An iron-based-organic framework (MIL-101(Fe)) was prepared using a simple one-pot method, aiming to simultaneously oxidize ROX through activating hydrogen peroxide and adsorption formed arsenate under simulated sunlight. The photoassisted MIL-101(Fe) (250mg/L) activating H2O2 (1.0mmol/L) system could remove 95.27\% of ROX within 120min. Moreover, the arsenate (As(V)) formed in this system could be adsorbed onto the surface of MIL-101(Fe) with 84.14\% of the total arsenic removal ratio. The main formed reactive oxygen species •OH and O2•- free radicals, attacked the As-C bond of ROX, generated As(V) and o-nitrophenol compounds and accelerated the removal process. The actual environment water matrix significantly promoted the removal ratio of ROX in this system.",

keywords = "Adsorption, Fe-based metal-organic framework, Hydrogen peroxide, Roxarsone",

author = "Sang, \{Lin Feng\} and Su, \{Shan Shan\} and Gao, \{Zi Wei\} and Wei Jin and Zhao, \{Ya Ping\}",

year = "2022",

month = jan,

day = "20",

language = "繁体中文",

volume = "42",

pages = "203--212",

journal = "Zhongguo Huanjing Kexue/China Environmental Science",

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publisher = "Chinese Society for Environmental Sciences",

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TY - JOUR

T1 - 光助MIL-101(Fe)活化过氧化氢氧化洛克沙胂及同步吸附生成的砷酸根

AU - Sang, Lin Feng

AU - Su, Shan Shan

AU - Gao, Zi Wei

AU - Jin, Wei

AU - Zhao, Ya Ping

PY - 2022/1/20

Y1 - 2022/1/20

N2 - An iron-based-organic framework (MIL-101(Fe)) was prepared using a simple one-pot method, aiming to simultaneously oxidize ROX through activating hydrogen peroxide and adsorption formed arsenate under simulated sunlight. The photoassisted MIL-101(Fe) (250mg/L) activating H2O2 (1.0mmol/L) system could remove 95.27% of ROX within 120min. Moreover, the arsenate (As(V)) formed in this system could be adsorbed onto the surface of MIL-101(Fe) with 84.14% of the total arsenic removal ratio. The main formed reactive oxygen species •OH and O2•- free radicals, attacked the As-C bond of ROX, generated As(V) and o-nitrophenol compounds and accelerated the removal process. The actual environment water matrix significantly promoted the removal ratio of ROX in this system.

AB - An iron-based-organic framework (MIL-101(Fe)) was prepared using a simple one-pot method, aiming to simultaneously oxidize ROX through activating hydrogen peroxide and adsorption formed arsenate under simulated sunlight. The photoassisted MIL-101(Fe) (250mg/L) activating H2O2 (1.0mmol/L) system could remove 95.27% of ROX within 120min. Moreover, the arsenate (As(V)) formed in this system could be adsorbed onto the surface of MIL-101(Fe) with 84.14% of the total arsenic removal ratio. The main formed reactive oxygen species •OH and O2•- free radicals, attacked the As-C bond of ROX, generated As(V) and o-nitrophenol compounds and accelerated the removal process. The actual environment water matrix significantly promoted the removal ratio of ROX in this system.

KW - Adsorption

KW - Fe-based metal-organic framework

KW - Hydrogen peroxide

KW - Roxarsone

UR - https://www.scopus.com/pages/publications/85123048539

M3 - 文章

AN - SCOPUS:85123048539

SN - 1000-6923

VL - 42

SP - 203

EP - 212

JO - Zhongguo Huanjing Kexue/China Environmental Science

JF - Zhongguo Huanjing Kexue/China Environmental Science

IS - 1

ER -

光助MIL-101(Fe)活化过氧化氢氧化洛克沙胂及同步吸附生成的砷酸根

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